Ch. 632Confrontation
Xu Yue revealed his identity and Zanpakuto-copying ability to Aizen, while Ichigo Kurosaki and the captains returned from Hueco Mundo and were defeated again. Genryusai Shigekuni Yamamoto then confronted Aizen, carrying the head of the Fire Extinguisher Prince and saying he had learned of Aizen's plan in advance.
- Aizen deduced that Xu Yue had impersonated Kaname Tōsen to copy captains' Zanpakuto and tried to turn him against the Soul Reapers.
- Xu Yue revealed his Quincy identity, and Aizen explained that he had planned to trap him in Hueco Mundo before recognizing his potential.
- Kisuke Urahara opened a Garganta, bringing Ichigo Kurosaki and several captains back to the World of the Living.
- Ichigo found Xu Yue, and the returning captains attacked Aizen but were defeated by his strength and Kyōka Suigetsu.
- Genryusai Shigekuni Yamamoto appeared with the Fire Extinguisher Prince's head and told Aizen that he had learned of his plan in advance.