Recaps

Xiao Yan won the Three-Year Agreement against Nalan Yanran, while Yao Wan revealed her power and helped him confront the strange flame within her. After the group reached Canaan Academy, Xiao Yan reunited with Xiao Xun'er and joined the new students in the Fire Energy Hunting Competition, where Yao Wan finally arrived.

• Nalan Yanran apologized to Xiao Zhan for breaking her engagement to Xiao Yan, and Xiao Zhan accepted that she and Xiao Yan had no future together.
• Xiao Yan cured Nalan Jie's Brand Poison, won the Alchemist Convention as Yan Xiao, and discovered that the Medicine Fairy had once helped Nalan Yanran.
• Xiao Yan and Nalan Yanran fought at the Three-Year Agreement, and Xiao Yan defeated her with Buddha's Fury Fire Lotus before Yao Wan stopped the blast and revealed herself as the Medicine Fairy.
• Yao Wan confronted Yun Shan and Protector Wu, severed their connection, and killed Protector Wu when he tried to flee.
• Back in Wutan City, Xiao Yan helped Yao Wan separate and seal the black-red flame inside her Life Spirit Flame, and Yao Lao warned that she would eventually need to refine it herself.
• Xiao Yan reunited with Xiao Xun'er at Canaan Academy, won the Inner Academy Selection Competition, and learned from Yao Lao that Yao Wan's sealed bloodline would eventually force her to return to her clan.
• Xiao Yan led the new students to victory in the Fire Energy Hunting Competition with Nalan Yanran, while Xiao Xun'er remained hostile toward her and Yao Wan.
• Yao Wan arrived at the end of the competition, delighting Xiao Yan and stirring Xiao Xun'er's hostility.

Xiao Yan entered the Inner Academy, reunited with Yao Wan and Little Fairy Doctor, and searched for the Yan Luo Branch needed to make the Soul Fusion Pill. After Little Fairy Doctor joined him at the academy and Yao Wan helped restrain her Woeful Poison Body, Xiao Yan completed the pill for Queen Medusa.

• Yao Wan welcomed the new students to the Inner Academy, where Xiao Yan and his companions established Pan Gate and investigated the Heavenly Flame Refining Gas Tower.
• Xiao Yan and Yao Wan grew closer as she placed a strand of heart fire inside him, while Xiao Yan searched the academy repository and met Zi Yan, who promised him herbs in exchange for making tasty pills.
• Xiao Yan left for the Black-Corner Region to find the Yan Luo Branch, obtained it from Thousand Medicines Workshop, and recognized Little Fairy Doctor, who followed him after he departed.
• Fan Lao attacked Xiao Yan on the road, but Little Fairy Doctor defeated and killed him, then agreed to accompany Xiao Yan back to Canaan Academy.
• Yao Wan examined Little Fairy Doctor's Woeful Poison Body and worked with Xiao Yan to restrain its poison, while Little Fairy Doctor and Xiao Yan acknowledged their feelings and concerns about his other relationships.
• Xiao Yan began refining the Soul Fusion Pill, and after a day and night of work he completed it and beckoned it into his hand as Queen Medusa watched.

Xiao Yan rebuilt Pan Gate, navigated tensions with Xiao Xun'er and Yao Wan, and took on Queen Medusa’s pill request while searching for a place to stay. He and Little Fairy Doctor confessed their feelings and agreed to begin a relationship carefully, leaving Xiao Yan intent on taking responsibility for the women he cared about.

• Xiao Yan gave Queen Medusa the Soul Fusion Pill, recovered in the Heavenly Flame Refining Gas Tower, and advanced to Two-Star Dou Ling before Medusa returned and agreed to cooperate with him for roughly a year.
• Yao Wan examined the mysterious charred branch, agreed to assess Xiao Yan’s compatibility with the Fallen Heart Flame, and warned him that women’s conflicts were not always misunderstandings.
• Xiao Yan spent time with Xiao Xun'er, while Yao Wan gave him a pill formula that Pan Gate used to sell Xiao Yan Pills and compete with the Medicine Gang.
• Yao Wan confronted Xiao Yan and Qing Lin about the pills and the rumors surrounding her and Xiao Yan, then told Xiao Yan to stay away for a while.
• Queen Medusa asked Xiao Yan to refine three Dou Ling Pills and one Imperial Zenith Pill within half a year, and Xiao Yan agreed while worrying about the danger to her enemies.
• With Medusa occupying his room, Xiao Yan struggled to find somewhere to stay before Yao Wan offered him temporary lodging and Little Fairy Doctor asked him to replenish her poisonous flame.
• Xiao Yan used the Netherworld Poison Flame to draw Little Fairy Doctor’s toxins into her Poison Body Embryo Pill, and she confessed her feelings and asked for a place in his heart.
• Xiao Yan admitted he wanted to take responsibility for Little Fairy Doctor, Yao Wan, and Xiao Xun'er, and Little Fairy Doctor accepted his promise while asking to wait before becoming physically intimate.

Xiao Yan’s tangled relationships came to a head as Yao Wan returned to the Yao Clan, while the Fallen Heart Flame erupted and forced him to fight alongside his allies. The story left Xiao Yan facing the crisis at the academy as Yao Wan presented her Life Spirit Flame to her clan.

• Yao Wan urged Xiao Yan to settle matters with Nalan Yanran and Little Fairy Doctor, and he apologized to Nalan Yanran before telling her about Little Fairy Doctor.
• Xiao Xun'er confronted Yao Wan over Xiao Yan, but Yao Wan restrained her Golden Emperor Sky Burning Flame and urged Xiao Yan to take responsibility for the women he loved.
• Xiao Li visited Canaan Academy, encouraged Xiao Yan to treat Xiao Xun'er and Yao Wan fairly, and told him Yao Wan had secretly supported the Xiao Family.
• Zi Yan emerged from her energy cocoon grown up and at Dou Emperor, then thanked Yao Wan for the Life Spirit Flame that had helped her advance.
• The Fallen Heart Flame erupted during the Strong Ranking tournament, and Yao Wanhua arrived to take Yao Wan back to the Yao Clan after five years away.
• Yao Wan revealed her real name, left Qing Lin with the Yao Clan, and defended Xiao Xun'er from Ling Quan before departing.
• Xiao Yan and his allies fought the Fallen Heart Flame and Han Feng, and Yao Lao took control of Xiao Yan’s body to kill Han Feng.
• Yao Wan returned to the Yao Clan with Qing Lin, displayed the Life Spirit Flame to the elders, and introduced Qing Lin to Yao Dan.