Vol. 2The Acting Captain
Shiraishi became acting captain of the Tenth Division while facing threats from Tokinada, Kaoru Tendō, and Sōya Azashiro. The volume ended with Isane asking him to save Unohana as she prepared to teach Zaraki.
- Shiraishi hunted Hollows with Sōya Azashiro, helped stop Genjirō’s attack, and became acting captain of the Tenth Division.
- Shiraishi settled into his new post and grew closer to Soi Fon and Nemu.
- Shiraishi and Soi Fon investigated murders linked to Tsunayashiro Tokinada as Aura Michibane joined the Gold Seal Unit and Aizen stole the clan’s Fullbringer corpses.
- Shiraishi pursued Tsukikage Yagyū to her hideout, where she captured Soi Fon and he activated his Bankai.
- Shiraishi escaped Tsukikage Yagyū’s Bankai, defeated her, and reunited with Kūkaku after securing her pardon.
- Kaoru Tendō allied with Tokinada as Shiraishi trained with Infinity and Soi Fon developed a dangerous Hakuda technique.
- Shiraishi fought Zaraki and trained while the captains uncovered a plot to attack Yamamoto and confronted threats including Sōya Azashiro.
- Isane arrived and begged Shiraishi to save Unohana, who was preparing to teach Zaraki.