Arc 11The Battle for Hueco Mundo
Liu Ziyun guided the rescue party through Hueco Mundo, saved Rukia and Ichigo, and helped turn several Arrancar against Aizen. After Ichigo recovered, Liu led him and Unohana through a Garganta to Karakura Town, where the battle had taken a dangerous turn.
- Liu Ziyun reunited with Nel, stopped Ichigo Kurosaki and the others from killing Pesche and Dondochakka, and helped the group pass Runuganga and reach Hueco Mundo’s core.
- At the crossroads, Liu Ziyun healed Nel’s mask and sent her with Ichigo Kurosaki, while the others entered separate passages and Liu continued alone.
- Liu Ziyun confronted Cirucci Sanderwicci, then helped Renji Abarai escape Szayelaporro Granz’s trap before leaving to rescue Rukia Kuchiki from Aaroniero Arruruerie and Zommari Rureaux.
- Liu Ziyun brought Rukia to safety, watched Ichigo defeat Grimmjow Jaegerjaquez, and stopped Nnoitra Gilga before Nel became Nelliel and fought him.
- Kenpachi Zaraki defeated Nnoitra, but Coyote Starrk abducted Orihime Inoue during a diversion, prompting Liu Ziyun to organize a rescue at Las Noches.
- Liu Ziyun found Ichigo near death after Ulquiorra Cifer pierced his chest, restrained Ulquiorra, and allowed Ichigo’s Hollow power to emerge before stopping Ichigo from killing him.
- Ichigo recovered as his Hollow power healed his chest, and Liu Ziyun persuaded Ulquiorra to help protect Hueco Mundo before Mayuri Kurotsuchi opened a Garganta to Karakura Town.
- Liu Ziyun, Ichigo, and Retsu Unohana arrived in Karakura Town as a giant Hollow released Gillians, while the Visored and Gotei 13 fought Aizen’s forces and Shūhei Hisagi struck down Kaname Tōsen.